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The ensuing radical undergoes C-S fragmentation to develop SO2, which becomes hydrated to sulfite/bisulfite (S(IV)). S(IV) is further oxidized to SO42- when you look at the presence of triplet sensitizers and air. We point out that the response sequence SO2 ⇌ S(IV) → SO42- is legitimate individually of the chemical framework for the model element and may represent a sulfate photoproduction system with basic quality for DOS. Our mechanistic investigation revealed that protein