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Meanwhile, Fe3O4/VAN@MIL-101(Fe) maintains the excellent catalytic activity in OERs and HERs after recycling for 5 times. Moreover, the introduction of magnetic Fe3O4 nanoplates into Fe3O4/VAN@MIL-101(Fe) can make it easily recyclable by magnetic separation, which can maximize its performance.Intense ns pulse laser excitation to nanoparticle colloids of a photochromic diarylethene induced an amplified cycloreversion reaction. The mechanism was explained as a 'photosynergetic response' coupled with nanoscale laser heating and the photoc