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Medical training programs need to implement a multipronged strategy to avoid sharps injuries, including increased utilization of products with sharps damage prevention functions and powerful instruction on safe maneuvering of sharps.We describe the very first catalytic generation of Fischer-type acyloxy Rh(II)-carbenes from carboxylic acids and Rh(II)-carbynoids. This novel class of transient donor/acceptor Rh(II)-carbenes developed through a cyclopropanation proce