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42 eV for this compound. Surface analysis revealed that the sample exhibits a surface area of 90 m2 g-1, which decreases to 30 m2 g-1 after the thermal annealing and the full conversion into ZnO. This difference in the surface area showed particular relevance in the stability of the measured optical properties. Particularly, the intensity of the photoluminescence signal was seen to be higher in the ZnO/ZnO2 sample and strongly dependent on the measurement atmosphere, highlighting its potential to be employed in the fabrication of opti