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The metal ions or conductive macromolecules intercalated hydrated vanadium oxides for aqueous Zn-ion batteries (AZIBs) have received increasing attention in recent years. The strategy for the preparation of the intercalated hydrated vanadium oxides has been achieved great advances but is still a huge challenge. In this contribution, we develop an interface-intercalation method to synthesize the polyaniline-intercalated hydrated vanadium pentoxide (V2O5·nH2O), denoted as PANI-VOH, as the cathode materials for AZIBs. The prepared PANI-VOH exhibi