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We believe that the structure of the surface crystallization phase is different from that of the bulk crystalline phase.We have investigated how nucleation and growth processes of ice are influenced by interfacial molecular interactions on some oxide surfaces, such as rutile TiO2(11, TiO2(10, MgO(10, and Al2O3(0001), based on the diffraction patterns of electrons transmitted through ice crystallites under the experimental configuration of reflection high energy electron diffraction (RHEED). The cubic ice Ic grows on the TiO2(11