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05% per cycle over 1000 cycles at 2.0 C), which are superior to those of most reported Li-S batteries coupled with state-of-the-art separators. Furthermore, it is shown that the excellent hindering of the shuttle effects enables a high areal capacity of 4.7 mAh cm-2 after 90 cycles at a high sulfur loading of 6.7 mg cm-2. Our work provides a feasible method for developing high-energy and long-life Li-S batteries, which might drive the commercialization of Li-S batteries.The capping reagent plays an essential role in the functional prope