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Dechlorane series flame retardants (DECs), e.g. Dechlorane plus (DP), have reportedly showed an increase in consumption since the phase-out of traditional brominated flame retardants (BFRs). Here we investigated DP and 7 structural analogues, as well as its 2 dechlorinated products in 76 surficial sediments from the Pearl River Delta (PRD), one of the three important manufacturing bases of China. The concentration of Σ8DECs varied from 28.1 to 38,000 pg g-1 dw in the PRD sediments, dominated by DP and Mirex. Spatially, sedimental DP con