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Bismuth sulfide (Bi2S3) is a promising material for thermoelectric applications owing to its non-toxicity and high abundance of bismuth (Bi) and sulfur (S) elements on earth. However, its low electrical conductivity drastically reduces the value of the figure of merit (ZT). In this work, we have synthesized three-dimensional (3D) hierarchical Bi2S3nanoflowers (NFs) by the hydrothermal route and further incorporated them with conducting polymer polyaniline (PANI) by simple chemisorption method. We have investigated the thermoelectric pr