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Six hypoeutectic Fe0.72Cr w Ni(0.28-w) alloys with a Cr/Ni ratio of around 0.8 were melted and solidified at various levels of undercooling. From the observed relationship between the undercooling and thermal plateau time, the hypercooling restriction as well as heat of fusion of Fe0.72Cr w Ni(0.28-w) melts are determined as a function of Cr mass fraction. A ratio of certain heat and total hemispherical emissivity associated with the Fe-Cr-Ni melts is calculated utili