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Besides, a solid-solution behavior is revealed in regards to the migration of NH4+ in the tunnel-like α-MnO2. Battery pack displays a splendid price ability of 83.2 mA h g-1 also at 10 A g-1. Additionally shows a higher power density of ∼78 W h kg-1 as well as a high power density of ∼8212 W kg-1 (considering the size of MnO2). What is more, the versatile MnO2//PTCDA pouch cell on the basis of the hydrogel electrolyte reveals excellent flexibility and good electrochemical propertie