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9% to 72.3%. The remarkable improvement suggests that the interphase modification holds great promise for high-performance metal sulfide-based anode materials for sodium-ion batteries. © 2020 WILEY-VCH Verlag GmbH Co. KGaA, Weinheim.In this work, rhombohedral KTi2 (PO4 )3 is introduced to investigate the related theoretical, structural, and electrochemical properties in K cells. The suggested KTi2 (PO4 )3 modified by electro-conducting carbon brings about a flat voltage profile at ≈1.6 V, providing a large capacity of 126 mAh (g-ph