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It is still a big challenge to simultaneously enhance the ionic conductivity, dendrite suppression capability, and interfacial compatibility of sulfide solid electrolytes. In this work, a novel Li7P2.88Nb0.12S10.7O0.3 solid electrolyte is prepared via Nb and O cosubstitution of glass-ceramic Li7P3S11. This sulfide-based electrolyte possesses a high ionic conductivity (3.59 mS cm-1) at 298 K, improved critical current density (1.16 mA cm-2), and excellent interfacial compatibility between the sulfide electrolyte and Li2S active material. T
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