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Doping Br, we, as well as in β-Fe2O3 results in transformation from a direct-band-gap semiconductor to an indirect-band-gap semiconductor because their particular atomic radii are too big; however, F- and Cl-doped β-Fe2O3 stay as direct-band-gap semiconductors. As a result of the deep impurity says associated with F dopant, this study is targeted on the effects of the Cl dopant on the musical organization structures of β-Fe2O3. Two impurity amounts are introduced when Cl is doped into β-Fe2O3, which n