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The photoluminescent (PL) intensity, excimer emission, and vibrational good framework for the fluorescence spectra had been seen to give information about period separation and solidification occurred in the dispersed droplets. The observations had been rationalized by analysis with ternary period diagrams calculated based on the Flory-Huggins principle. Upon irradiation with a linearly polarized laserlight at 488 nm, the azo polymer parts into the P(MMA-co-PyMA)/PCNAZO JPs were seen t