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Sharp branches of gold nanostars are critical in tuning the plasmonic properties of the nanostars and making the most of the activities in surface-enhanced Raman scattering (SERS). The communication between the capping ligands and nanostars plays a vital part in deciding the morphology regarding the limbs on the silver nanostars. In this essay, we show that 4-mercapto benzoic acid can effortlessly get a grip on the morphology of branched silver nanostars, and these gold na