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tissue discrimination (ARI=0.414 vs. 0.157 with T2WI ). T2 mapping provided RFs with moderate to substantial repeatability and reproducibility ICCs, along with the most preserved discriminative information. 1 TECHNICAL EFFICACY 1. 1 TECHNICAL EFFICACY 1.We develop hetero-nanostructured black phosphorus/metal-organic framework hybrids formed by P-O-Co covalent bonding based on a designed droplet microfluidic strategy consisting of confined and ultrafast microdroplet reactions. The resulting hybrid exhibits large capacitance (1347 F g-1 )