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Finally, the existing challenges and limitations of N2 fixation are proposed, as well as possible future perspectives, which will provide a platform for further development of advanced Mo/W-based N2 reduction systems.The phenylalanine radical (Phe˙) has been proposed to mediate biological electron transport (ET) and exhibit long-lived electronic coherences following attosecond photoionization. However, the coupling of ultrafast structural reorganization to the oxidation/ionization of biomolecules such as phenylalanine remains unexplored.