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The hydroxylated intermetallic Co3Mo features an optimal hydrogen-binding energy to facilitate adsorption/desorption of hydrogen intermediates for hydrogen molecules. Connected with high electron/ion transport of bicontinuous nanoporous skeleton, nanoporous copper supported Co3Mo electrodes exhibit impressive hydrogen development reaction catalysis, with negligible beginning overpotential and low Tafel slope (~40 mV dec-1) in 1 M KOH, recognizing current thickness of -400 mA cm-2 at overpotential of