https://www.selleckchem.com/pr....oducts/FK-506-(Tacro
Thus, the present study unveils the role of steric and electronic effects of the ligand towards mechanistic modification during olefin epoxidation.A 1,2-dicarbonyl moiety on a cage-opened fullerene skeleton is one of suitable building blocks for the further derivatization. Herein, we discuss the chemical transformation of a 1,2-dicarbonyl compound into β-oxo-phosphorus ylide, acid anhydride, and α-methylene carbonyl derivatives. Despite possessing a sterically small methylene unit in the last one, the release of an encapsula
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