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Protein Ⅰ in soil natural matter (SOM) was reduced by managing CH and carboxyl team OH, which suggested that protein Ⅰ ended up being sedentary. Protein Ⅰ oxidation after regulation ended up being decreased notably. Protein Ⅰ was the main active organic matter to fully capture OH. When the relative reactivity coefficient KTPH/SOM (the ratio of TPH oxidation to SOM oxidation) and KTPH/protein we (the proportion of TPH oxidation to protein Ⅰ oxidation) h