https://www.selleckchem.com/pr....oducts/sch-442416.ht
The role of peripheral groups (PGs) on dendrimers in the spontaneous higher-level organization of hierarchically assembled nanofibers was investigated in a series of POSS-based dendritic gelators (POSS-Lys-X, X -Boc, -Cbz, -Fmoc, etc.). We demonstrate that the PGs not only affect the gelation ability in solutions, but also the construction of orderly entangled fibrous supramolecular networks, e.g., "loofah-like" networks. Attributed to the PGs (especially the -Boc group) causing a lower cooperative assembly, the steady state with the
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