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Compared with inorganic long-lasting luminescent materials, organic room temperature phosphorescent (RTP) ones show several advantages, such as flexibility, transparency, solubility and color adjustability. However, organic RTP materials close to commercialization are still to be developed. In this work, we developed a new host-guest doping system with stimulus-responsive RTP characteristics, in which triphenylphosphine oxide (OPph3 ) acted host and benzdibenzo)phenothiazine dioxide derivatives as guests. Turn-on RTP effect was real