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The results indicated the better performance with the aid of heterogeneous catalysts due to the generation of more active species. Intermediate products at smaller molecular weight were obtained through various types of pathways under heterogeneous photo-Fenton degradation of fluoroquinolones, implying a practical application with biological treatment processes for fully mineralization.3D graphene-based materials are promising adsorbents for environmental applications. Furthermore, increasing attention has been paid to the improvement of 3D graphene adsorbe