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© 2020 WILEY-VCH Verlag GmbH Co. KGaA, Weinheim.All-inorganic solitary ion magnets representing paramagnetic ions integrated in a crystalline diamagnetic matrix are evaluated. Key outcomes and advantages of this process when compared to the common strategy based on molecular metal complex substances are thought, plus some unsolved issues and future views are discussed. © 2020 WILEY-VCH Verlag GmbH Co. KGaA, Weinheim.A series of unique acyclic, macrocyclic and m