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Similar to Re-2OH (2OH = 4-phenyl-6-(phenyl-2,6-diol)-2,2'-bipyridine), 1 and Mn-1OH display a selective reduction of CO2 to CO. In the case of the Re bipyridine-type complex, the formation of a relatively stable Re-O bond and a preference for phenolate-based reactivity with CO2 slightly inhibit the electrocatalytic reduction of CO2 to CO, resulting in a low TON value of 9, even in the presence of phenol as a proton source.Thermoresponsive polymers with lower critical solution temperatures (LCSTs) are of significant interest for a wide
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