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Remarkably, we uncover the interplay between an upper state of marked multiexcitonic character and a low-lying CT state in balancing the splitting efficiency, which anticipates their major role in defining future guidelines for the molecular design of D-A copolymers for iSF.Cyclic dinucleotides (CDNs), agonists of stimulator of interferon genes (STING), are promising agents for immunotherapy. However, the application of CDNs has been limited by their instability and low transmembrane efficiency. Here, we introduced a conjugated adjuvant