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In addition, the different isotopes of bromine and chlorine can be clearly distinguished at the same time. Finally, the home-built portable Raman spectrometer was utilized to analyze the vibrational modes and get the "spectral fingerprint" of VOCs. All the results indicate that the direct online detection performed by the LIBS and SPAMS techniques could provide elemental and isotopic information of halogen atoms in atmospheric VOCs.We investigate the formation of rotational coherence of N2+ resonantly interacting with an intense femtoseco