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SW does not favor adsorption of these small molecules, as the process for each is endothermic. In the case of BN, CO adsorbs strongly but CO2 only weakly. Vibrational frequencies of notable modes localized at the adsorbed molecules are analyzed and suggested as measures for identification of the defect type. Through a simple comparison of adsorption characteristics of the molecules on these defects, we propose dh-BN with VN to be a good catalyst candidate for CO2 hydrogenation.The intense far-red absorption and emission features have made
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