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In order to control the magnetic properties and electronic structures of black phosphorene (BP) monolayer, the structures, electronic and magnetic properties of non-metallic elements doped BP monolayer without or with defects including P vacancy (VP) have been studied by density functional theory (DFT). Defective BP appears ferromagnetic metallicity, and the magnetic moment is 0.086 μB. The magnetism mainly comes from the spin polarization of P atoms near the defect point. For non-metallic elements doped intrinsic BP, system doped with B