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The measurements of a monoterpene (α-pinene) were performed by the PTR-TOF-MS instrument at an urban site of India from mid-January to March 2014. The daytime concentration increased from 0.15 ppb in the second-half of January to 0.40 ppb in the second-half of March. Both the nighttime and daytime ratios of α-pinene/benzene in the second-half of March were 2-3 times higher their respective values from mid-January to first-half of February. The ratios of α-pinene/benzene increased from ∼0.27 ppb ppb-1 at lower temperatures to ∼0.51 ppb p