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Moreover, the metalloreceptors showed a remarkable fluorescence increase (at ∼584 nm) upon the addition of hydrazine, without the interference of other amines in CH3CN/H2O (6/4, v/v). Interestingly, fluorescence enhancement was observed within live HeLa cells upon hydrazine addition, which is caused by the efficient photoinduced electron transfer process.A novel manganese-catalyzed C-H activation methodology for selective hydrogen isotope exchange of benzaldehydes is presented. Using D2O as a cheap and convenient source of deuterium, the