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Obtaining a large open-circuit voltage (VOC ) and high short-circuit current density (JSC ) simultaneously is important in improving power conversion efficiency (PCE) of organic photovoltaics. The ternary strategy with using a higher lowest unoccupied molecular orbital (LUMO) level nonfullerene acceptor (NFA) guest can achieve increased VOC , yet JSC is decreased or maintained, so it's still a challenge to offer increased VOC and JSC values concurrently via the newly presented VOC -increased ternary strategy. To overcome this issue, a