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For example, potato is an important source of DIN in rivers of some upstream sub-basins. Our results may help to prioritize the dominant crop sources for management to mitigate N pollution in the future.Metal-organic frameworks (MOFs) have been explored as crystal sponges (CSs) to organic substrates, but attention had rarely been paid to inorganic substrates. Herein, hierarchical zirconium-based MOFs exhibiting different topological structures had been fabricated by modulating the functional groups of the V-shaped linkers, including a new