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The reactive sites susceptible to nitrating in NOM molecules are not limited to phenolic moieties. We found that aromatic carboxylate moieties could be in situ transformed to phenolics by SO4•-, thus contributed to nitrophenolic byproducts formation as well. Considering the ubiquitous presence of NH4+ in the environment, formation of nitrophenolic byproducts will be widespread when SO4•- is applied for onsite remediation, which should be taken into consideration when evaluating the feasibility of this technology.Microplastics provide a