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In this Review, the recent progress of polynary metals and heteroatoms SACs is summarized. Finally, the barriers to tune the activity/selectivity of SACs are discussed and further perspectives presented. © 2020 WILEY-VCH Verlag GmbH Co. KGaA, Weinheim.Migration and differentiation of bone marrow-derived mesenchymal stem cells (BMSCs) is an important biological process in tissue regeneration. Nano-structured titanium materials are believed to play a fundamental role in dental and orthopedic applications. However, the protein ad