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The result of 1 with ZnCl2 and AlCl3 resulted in the forming of chelate complexes 5 and 7, correspondingly, while treatment with EtAlCl2 and GaCl3 kinds monodentate complexes 8 and 9. X-ray evaluation of 4 indicated that the copper is in the spiro center for the two five-membered rings. Additionally, the copper(I)chloride has not been oxidized but dissociates to Cu+ and [CuCl2 ]- . All of the compounds are described as mass spectrometry, elemental analysis , NMR spectroscopy, and single-crystal X-ray diffracti