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7 cells). Compounds 2, 3 and 6 showed potent anti-inflammatory effects than the positive control (indomethacin, IC50, 24.0 μM) with IC50 values of 11.52, 8.13 and 21.27 μM, respectively. Four undescribed oxylipin vanillyl acetals with four stereogenic carbons were isolated from the herbs of Solanum lyratum. A comprehensive set of spectroscopic methods were used to elucidate the structures and relative configurations of 1-4. The absolute configurations of the naturally occurring compounds are assigned as 7S, 9'S, 10'S, 11'R at the site o
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