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This study presents a novel and facile strategy for fabricating fire-resistant, ultraviolet (UV)-shielding, and tensile-enhanced polylactide (PLA) composites using two-dimensional (2D) MXene (Ti3C2) flakes chemically modified with 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO). The thermal and burning performances of PLA composites were demonstrated by the limiting oxygen index, UL-94 test, and cone calorimetry. The UV-shielding and tensile performances were also examined. The results revealed that PLA/Ti3C2-DOPO (3 wt %) displayed a V-0 rating i