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By expressing the MP law as a function of estimated Fdiff after a certain period of time, we provide a uniform description of the changes in periodicity for both small and large reservoir volumes. Such modification should make the MP law a more robust tool for studying LP systems.Oxygen reduction reaction (ORR) is one of the most important electrochemical reactions. Starting from a common reaction intermediate *-O-OH, the ORR splits into two pathways, either producing hydrogen peroxide (H2O2) by breaking the *-O bond or leading