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In any case, the structure of this metabolite couldn't be assured based on the available fragmentation, and the analytical reference standard should be synthetised for unequivocal identification. Analytical standards of six different theoretical metabolites were injected to allow right assignment of positional isomers in hepatocyte incubations (Fig. 2). ADB-CHMINACA M2 (RT, 9.sixty eight min), M3 (two stereoisomers at 5.09 and 5.20 min), M7 (6.for