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Flame retardants have important theoretical research and applied value for lithium-ion battery safety. Microcapsule flame retardants based on ammonium polyphosphate (APP) and aluminum hydroxide (ATH) were synthesized for application in lithium-ion batteries. First, the ATH-APP was prepared by coating a layer of ATH on the surface of the core APP. Then, the ATH-APP was encapsulated by poly(urea-formaldehyde) (PUF) to obtain en-ATH-APP. The structure and flame-retardant property of en-ATH-APP, the influence of en-ATH-APP on the thermal st