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The rate-determining action for the dehydration of ethanol on HB had been thus ascribed into the dehydrogenation associated with methyl selection of the ethyl species on the HB sheets, accompanied by the instant desorption of ethylene. These results reveal that the catalytic ethanol dehydration process on HB involves the hydrogen atoms for the HB sheets. The obtained mechanistic insights are anticipated to advertise the request of HB sheets as catalysts.Atomically accurate silver nanoclusters pr