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A synergetic aftereffect of low reabsorption, low defect concentration, and large absorptivity leads to high-efficiency cascade energy transfer and also a marked improvement in security. Moreover, the h-BN@PMPB composite powder shows a narrow-band green emission band peaking at 532 nm with a complete width at half maximum of 32 nm, while the white LED backlight reaches an extensive color gamut 106.1% of the National tv Standards Committee (NTSC). This work reveals an over-all synthesis method for