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In this regard, the shrinkage of octahedral MnO6 provides a robust framework additionally the expansion of tetrahedral LiO4 facilitates an easy electrochemical process. Also, the lead polyhedral Li1+xNi0.05Mn1.95-xO4 samples present the uncovered (11, (10, and (111) crystal planes, which supply the favorable Li+ ions diffusion/transmission channel and alleviate Mn dissolution. Due to these merits of polyhedral structure and Li-Ni co-doping, the optimized Li1.02Ni0.05Mn1.93O4 exhib
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