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The result of paramagnetic a-bromoketone produced a vinylphosphonate in the Perkow effect. Paramagnetic a-hydroxyphosphonates might be afflicted by oxidation, elimination and replacement responses to make different paramagnetic phosphonates. The synthesized paramagnetic phosphonates turned out to be useful synthetic building blocks for carbon-carbon bond-forming responses in the Horner-Wadsworth-Emmons olefination reactions. The unsaturated compounds accomplished might be transformed