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The goal of this work consists in supplying a comprehensive recognition associated with the main major oxidation products of diisopropyl ether (DIPE), very promising among etheric oxygenates. The Cl-initiated oxidation of DIPE is examinated by making use of a vacuum ultraviolet (VUV) synchrotron radiation at the Advanced Light Source (ALS) of this Lawrence Berkeley National Laboratory (LBNL). Products are identified on the basis of their mass-to-charge ratio, model of pho