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0 × 10-3 S/cm even when the ATP concentration up to 30 wt %. These novel findings are very useful for the fabrication of high temperature resistant electrochemical devices and liquid crystalline nanocomposite materials.The surfactant properties of amphiphilic hyperbranched polyglycerols (HPGs) were investigated. The HPGs were prepared by ring-opening multibranching polymerization of glycidol using hydrophobic initiators of varying size and structure. The cloud points for all HPG surfactants were found to be 80 °C in deionized water