https://www.selleckchem.com/ph....armacological_epigen
A detailed study for the synthesis of dinickel(II)-thiolate and dinickel(II)-hydrosulfide complexes and the complete characterization of the relevant intermediates involved in the C-S bond cleavage of thiolates are presented. Hydrated Ni(II) salts mediate the hydrolytic C-S bond cleavage of thiolates (NaSR/RSH; R = Me, Et, n Bu, t Bu), albeit inefficiently, to yield a mixture of a dinickel(II)-hydrosulfide complex, [Ni2(BPMP)(μ-SH)(DMF)2]2+ (1), and the corresponding dinickel(II)-thiolate complexes, such as [Ni2(BPMP)(μ-SEt)(
Like
Comment
Share
