https://www.selleckchem.com/pr....oducts/sodium-dichlo
These mechanistic insights are expected to advance the design of efficient bioinspired Mn cubane water-splitting catalysts.We report the discovery, development, and mechanism of a nickel-catalyzed annulation reaction between o-haloarylimines and electron-poor olefins. The reaction produces two adjacent anti stereocenters and a free secondary amine. Spirocycles are formed from cyclic imines. We characterized the key oxidative addition intermediate and identified a major path leading to competing homocoupling products.
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